hey everyone I've
been developing a
technique to electro polish aluminum
I haven't found much on the internet
regarding this technique so I thought
I'd share what I've learned this is an
unknown aluminum alloy and as you can
see I have electric polished it here and
this is the stock finish this is another
bar this is known to be 6061 aluminum
and the finish right in this area here
is the mill finish that comes on the
metal you know as I bought it from
McMaster and as you can see even without
any mechanical polishing whatsoever you
get this nice finish here so let me tell
you about it you don't need much exotic
equipment to electro polish alamin 'm
I'm going to show this method with just
pure phosphoric acid and you can get
this on eBay it's actually not even that
expensive and a thermometer a glass or
plastic vessel that can hold about 100
degrees C or less liquids then you need
something heat up the solution I'm going
to use this immersion heater but you
could also use a hot plate or a stove or
something with a heat spreader like that
you need an aquarium air pump and an air
stone or a pump inside the vessel that
can swirl the liquid around it creates
majid ation and a standard car battery
charger for a power supply of course if
you have better equipment you'll get
better process control so if you have a
bench supply that can do constant
voltage and constant current control
it'll be better if you have a heat
controlled hot plate it'll be better but
this is sort of the basic minimum set of
equipment this is 75% phosphoric acid
and in comparison to other concentrated
acids it's actually not such a dangerous
thing to handle but you'll still want to
use gloves splash protection and eye
protection so I'm going to pour out
about half a beakers worth in fact if
you're doing this on larger parts you'll
want to have a much larger container of
acid just to keep the temperature more
stable just to demonstrate this
technique I'm just going to use a small
amount of acid here I'm going to put the
immersion heater in the acid and then
add this thermometer here and we're
targeting about 75 degrees Celsius okay
we're at temperature so I'm going to
take the thermometer out
and add to scrap pieces of stainless
steel and these will form half of our
circuit I'll connect these together
electrically with an alligator clip
okay I've got the air pump turned on and
I'm going to put the air stone in there
and then use a clip to hold it to keep
it from floating I've got the battery
charger on and the negative side
connected to the two stainless plates
that are there I'll connect the positive
side to the piece that we want to polish
and then add that to the bath and make
sure of course that it doesn't short out
okay after just a few minutes let's see
what we've got here I'm going to use
some distilled waters to get the acid
off right away
as you can see it's done a really good
job of polishing it already in just a
few minutes here's the piece we just
polished and you can note a couple
things about it one is that the part of
the metal that wasn't submerged actually
got a little damaged from the acid
spraying on it so you can't halfway
submerged parts that you want to electro
polish you pretty much have to submerge
the whole thing second there is a bit of
pitting going on in here you can see
there's sort of a rough surface and it's
actually a little bit better here near
the surface but down here or the surface
of the polishing solution but down here
there's this pitted texture this is
probably caused by the electrochemical
action of the polishing bath and I'll
show you why that is in just a minute
I was able to find a chart on the
internet that helped explain some of the
results that I was getting this shows
voltage on the y-axis and current
divided by area that's the area of the
part that we're going to polish on the
x-axis and there's three distinct zones
that are identified by the slope of the
of the curve so in this first region
it's mostly linear but then there's a
dip in a relatively flat region and then
it takes off over here and so what's
happening is that in this sort of low
current region over here what we
actually are doing is etching the
aluminum not polishing it and this
happens because the etching takes place
preferentially at these grain boundaries
and what happens is we just end up
digging into the material a little bit
if we increase the amount of current per
unit area what happens is this is
complex and I actually don't fully
understand it myself but the solution
will form a viscous layer on top of the
surface and this actually has the effect
of reducing bumps and so if there were
if there was a sharp edge sticking out
of the part you know a little burr then
that burr is exposed on more sides than
all these other flat regions are and so
it gets preferentially beaten down
polished away because it has more
surface area on this little spot and the
density of the fluid and the
concentration of the electrolyte and the
base metal and the voltage and
everything basically affects this whole
thing of course I tried to collect data
that looked like this graph and set my
oscilloscope up to to try to generate
this but
I couldn't do it so I don't know if this
applies to specific blends of
electropolishing solutions most of the
patents and other information that I
found on the Internet
did not suggest using pure phosphoric
acid they almost always suggested blends
of sulfuric and phosphoric and sulfuric
and ethylene glycol and all kinds of
other things and I tried lots of those
blends and still was never able to
produce a graph like this but anyway the
reason that we were seeing pitting like
this over here is because it much higher
current densities there's a lot of gas
produced and if a gas bubble is on the
surface it can't be electro chemically
polished because there's a big gas
bubble in the way there's no liquid
making contact so you can't go too fast
basically because you're limited by this
hydrogen production problem one thing
that helps is adding a little bit of
surfactant to the polishing solution and
I forgot to mention earlier that you
could put a drop of dishwashing liquid
in there just to lower the surface
tension and help these bubbles break
away from the surface more easily to sum
up the recipe that I recommend is 75%
phosphoric acid at 75 degrees C and you
want to use about a hundred milliamps
per square centimeter and conveniently
this comes out to be just about right
for battery charge or voltage now kind
of in the neighborhood of 14 volts or so
okay see you next time bye best way to earn money from home, make instant money online absolutely free, trusted online money making sites, online income site, best online earning, money online, earn money from home, earn dollars online, earn money online, earn money online 2019, earn money online by typing pages, earn money online daily, online work at home and earn money, online earning, earn money online free, online money earning sites, earn real money online, e commerce ideas to make money, easiest way to earn money online, best way to earn money online, make money from home, make money online free, money making sites, earn from home, real ways to make money from home, online income ideas, make real money online, top online earning websites, earn money online fast,

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