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today on Applied
Science I'd like to
talk about my adventures in making gecko
tape if you haven't heard gecko tape is
sort of an alternative to the currently
available adhesive tapes
it actually works by a different
mechanism and it's not really a
commercial product yet but it's gotten a
lot of press in sort of popular science
articles and so it has a few attractive
qualities that make it better suited
than these commercial adhesive tapes so
first let's talk about how these
actually work each one of these tapes
has a layer of adhesive on it there's
actually a chemical on here and the
reason it's sticky is because it makes a
chemical bond with whatever you're
sticking it to and so the problem with
this is if you get it wet or if it gets
dirty the chemical becomes coated with
water or the dirt and then that the tape
is no longer sticky so if you're
constantly taking the tape off and
replacing it eventually the adhesive
will wear out and the tape is no good
anymore
the difference with gecko tape is that
this works by a mechanical method it's
actually using a different sort of
molecular bonding and so in this video
I'm going to talk about all the things
I've tried so far unfortunately it's not
working just yet but with your help
hopefully it will like the name implies
gecko tape is actually modeled after the
foot of a gecko and so part of the
reason that the geckos foot wouldn't
work with a conventional adhesive like
this is because it would quickly become
loaded with dirt and the gecko wouldn't
be able to stick and walk upside down
which is critical to its survival so the
gecko tape is sort of our answer or at
least our you know modeling of this sort
of natural phenomenon and the trick is
that the geckos foot has a whole bunch
of hairs on it and the hairs get into
very intimate contact with the foots
with the surface that the foot is
stepping on and it's these small
intermolecular bonding forces that
produce an attractive force between the
hair ends and the surface that it needs
to stick to
so most surfaces aren't perfectly flat
they're not atomically flat so if you
want to get something into very close
contact with it it needs to be very
conformable and even something soft like
this silicone rubber it's really not you
know you'd think well if the silicone
rubber has a flat surface here and we
put it down on something flat at the end
back but not really at the microscopic
level there's always going to be you
know hills and valleys and it's not
going to make really great contact so
nature's solution to this problem was to
have a structure that has very small
hairs and when you push that down onto a
surface sort of the end of each hair
will make really good contact with the
surface and then you know if you have
millions of these little hairs it's
basically almost as good as having a
solid flat piece into you know perfect
atomic contact so whereas the commercial
adhesive tapes use perhaps hydrogen
bonding or something like that where you
have this chemical adhesive layer that's
going between the tape and the surface
the gecko tape works by Van der Waals
forces which are present between all
molecules as far as I know but the trick
is that you have to get the two surfaces
really really close together like less
than you know one nanometer a few
nanometers or something it basically has
to be in contact and as I mentioned even
if you cast a perfectly flat piece of
tape and you put it on to a perfectly
flat object like this it's not even
close to good enough contact you really
need this conformable architecture so
the gecko has adapted sort of a two
layer system where it has pillars coming
off of its foot and then there's even
hairs that are a finer structure even
coming off of that and so between the
pillars and the hairs it can really
conform and have a huge amount of
surface to surface contact the actual
material itself of the hairs and the
thing that it's walking on is not
particularly important it's just the
fact that it's such in such close
contact is what makes this whole system
work so anyway so I'm really interested
in this and I searched the internet for
instructions on how to make gecko tape
or at least you know what the techniques
are being used in these research labs
and lo and behold I actually found
detailed dedicated instructions for how
to make your own gecko tape at home and
if you had part numbers for all the you
know stuff that you'd need and this is
sort of the key ingredient here so the
idea is that you make the Gecko tape by
casting the silicon rubber and it's
pretty easy you just mix it up kind of
like two-part epoxy but the the ratio is
much greater than one to one
and you pour this onto a mold and
hopefully the mold has you know holes in
it just like these these we want to form
pillars and so the mold has to have
holes in it so we're going to pour the
silicone on to that and then D mold it
and then you will have like you know
this forest of pillars coming off and
that's the structure we need to make
this whole thing work so it sounds
reasonable and the instructions are very
clever so they're going to use this
interesting membrane here too
to make our silicone cast and of course
I'll put links to all of this in the
description so definitely check that out
these are actually pretty cool this
deserves a little one minute side note
all by itself this is a track edged
membrane filter and so the idea as I
mentioned we want a whole bunch of
little holes in here so that when we
cast our silicone rubber it goes down
into the holes and we end up with this
forest of pillars so the way that you
make this track itched membrane is you
start with a really thin sheet of
polycarbonate standard you know just
just like unbreakable safety glass or
whatever and you expose it to a
radiation source I believe it's probably
a beta source but I couldn't quite find
out for sure and the trick is the beta
particles are going really fast and
they'll actually go all the way through
the polycarbonate sheet because it's so
thin we're talking 10 or 20 micron or
something like that and then you put
this into an etchant and where the beta
particles have gone through this really
thin polycarbonate sheet it's actually
weakened the chemical structure of the
plastic a little bit and the etchant
will attack only the weakened areas so
as the beta particles go screaming
through these sheets then you put this
into the etchant bath you'll end up with
a hole edge in just the places where the
particle has gone through and the longer
that you leave it in the etchant bath
the wider the holes will become because
it sort of edges from the inside of the
hole out so it's a really easy way to
get a very uniform hole size so let's
take a look at one of the what if one of
these looks like under the scanning
electron microscope this is the millah
pore membrane that was mentioned in the
instructions for making gecko tape and
it has a 5 micron hole size and it's
pretty much identical on the top and the
bottom
I also bought GE Walkman brand filters
and these have a three micron hole size
but I can tell they're built or they're
made with a different process because
the one surface is very shiny and the
other surface is very rough
so clearly the etchants that they used
to make these filters was a little
different it actually attacked the
polycarbonate a bit more so you can kind
of tell which sizes which side of the
filter was exposed to the etchant anyway
so I thought that was pretty cool what
you do according to the instructions is
you take one of these filters with the
tiny holes in it and put it down onto
some double-stick tape and then you pour
the silicon you know you mix up a batch
of silicon this is actually tin cure
silicone RTV silicone from tap plastics
and amazingly enough the silicone will
actually flow down into those five
micron holes all the way to the bottom
even so through the thickness of this
membrane and then when it cures and you
peel this off you end up with the
structure we wanted to make this you
know simulated gecko foot and it all
works the way it's supposed to but the
structure that it creates doesn't
function as well as a gecko foot in fact
it functions less well than a solid slab
of silicon as I'll show you so just to
give you a rough idea of how good the
silicone is by itself even though I
spent a lot of time saying well you know
if you put something in contact like
this even though the contact area even
though it's flat is not very good
because there'll be you know microscopic
hills and valleys it's actually pretty
good so just to give you sort of an idea
of how sticky this thing is I just sort
of stuck it down like that with almost
no pressure applied I can pull this
heavy piece of plastic around if you can
see then okay so then this is the
silicone that I made by casting the
silicone in the membrane just like it
was said in the instructions and if we
put this on here I know that it's kind
of hard to see on the camera you really
need to get a tactile sense of this no
matter how much I baby this and no
matter how careful I am the friction
coefficient with the so-called gecko
tape is way way worse in fact this is
almost sort of an anti friction material
like this is really kind of it's worse
than then just flat I mean it's
basically worse than a lot of other
things so it doesn't work and then I
started searching around on the Internet
a bit more and found someone's thesis or
dissertation where they actually
mentioned these instructions and how it
couldn't possibly work for a lot of
reasons that we're going to get into so
you know I wanted to see it first so
let's take a look with the scanning
electron microscope again at what these
pillars look like okay you can see that
yeah the casting process did work and
you can also see that the direction of
the tracks that are etched through these
plastic is not you know they're not
perpendicular to the surface they're
actually kind of all different
directions
and that's because the radiation source
doesn't just shoot out you know beta
particles in one direction they're kind
of going all different directions so
that's one problem the other problem is
that the pillars have a really high
aspect ratio they're kind of like wet
noodles just you know falling down over
there because they're too long and so I
mentioned that the thickness of this
membrane is like 10 or 20 micron or
something like that
this is one of them right here you can
see that it's really really thin in fact
it's so thin that just the static
attraction makes it really kind of
difficult to handle it's it's is thin
stuff but it's still way too thick so
the relative thickness of this thing
compared to the 5 micron you know pillar
diameter is so high that the pillar just
folds over and we don't really want it
to fold over like that what we want is
the thing to be you know fairly stiff so
then we put this down on to the surface
the pillars kind of have enough rigidity
so that the ends of the pillars touch
the surface and make a good contact
there if they're all just flopping
around then you know the whole gecko
thing doesn't work so I did a little bit
more searching and found another group
that moves instead of doing straight
pillars like this they were doing angled
kind of wiper blades almost you know
again microscopic we're talking you know
a couple microns thick or a couple
microns long and maybe a pitch of 500
nanometer and I thought well that's
pretty cool maybe there's actually a
structure that I can find kind of
around in everyday life that sort of
mirrors this because they were using
photolithography to make their parts
which I'll talk about a little later and
I came up with the idea of casting the
silicone on to really really fine metal
files so I did a little bit of research
and found out that you can get these
swiss metal files that are quite a bit
finer than the the so called american
grades of files so typically a smooth
file is the smoothest thing you can get
commonly at least you know in this
country around here if you go to your
local hardware store in the US a smooth
file is considered the final the finest
thing you can get but if you go online
to a specialty store you can get this
Swiss file and I've never seen a file
this fine this thing is really really
fine
I think the pitch is around 20 or 30
thousand inch I'll put the exact numbers
in the description
but anyway I made a whole bunch of
different castings with different files
and different viscosities of silicone
you can kind of thin the silicone and
make it into a stiffer or more flexible
stuff and you know as you might expect
the results aren't that great but they
are unidirectional surprisingly so I did
find that with a specific file pitch I
kind of have to put a little bit of
weight on the tape too to make this work
but you can kind of see in one direction
it works about that well and then in the
other direction it's not even close to
as good and the reason is that the the
teeth are you know asymmetric and when
the teeth are getting pulled sort of in
their direction they kind of fold down
and create more contact with the surface
that they're bonding to if they're going
the wrong way
when you pull them this way they just
sort of buckle and flap around and they
don't create that great contact so if
you are interested in using gecko tape
is kind of a robotic foot or grabber or
something having a unidirectional
adhesive surface is actually very nice
because you can make like a wall climber
you know gravity is always trying to
pull you down so you can make the wall
climber you know you can make the foot
basically work just the way you want so
if you put a lot
wait on it you can get Goods diction and
then to lift the foot you actually push
it upwards and it will instantly detach
because it's you know a one a one
directional gripper so after this I
realized there's no way I could get a
metal file that was fine enough to get
you know close enough contact again
another problem with the metal file is
that the teeth are sharp on the top but
unfortunately we're making a casting and
we actually want the teeth to be really
sharp in the bottom because when we do
the casting and peel it off it's
actually the tips of the casting that
are going to be interacting with our
surface and that's going to be formed by
the bottom of the of the file so you
know that basically just the
manufacturing this isn't really made for
it even though it's a good idea it was
it's not really going to work out so
then I had another great idea what about
using a CD as the former so that's
pretty cool so we're talking this thing
has a pitch between the pits and lands
with you know a few micron or something
on that order but I didn't know how deep
they were so I was able to make a
silicone cast of a CD and it is this one
so I came home one day after letting my
silicone cast there and tried it out and
I was actually really excited a it works
really well in fact way way better than
the files way better than the you know
official gecko tape instructions and
then I you know of course tried it
compared to the actual just flat cast on
glass silicone and it's it's not even
quite as good as that so so clearly
there's still some more work to be done
here the biggest problem is that the
aspect ratio of these magic pillars is
not quite right it needs to be about
four to one so if the if the spacing
between the pillars or if the size of
the pillars is on the order of 500
nanometer that means the depth has to be
2 micron and in the CDs case if it's
like a few micron in diameter then we're
going to be like maybe 4 to 8 micron
deep or something like that and so far I
haven't found any kind of easily
accessible mold that has this correct
aspect ratio and a high density of the
pillars the other problem with the track
etched membrane is that these you know
wet noodles are just spread out way too
far if you want like dense packing to
make this thing work
so all of the research groups that are
doing this are pretty much using
photolithography which involves you know
casting a photosensitive layer and you
can control the thickness of the layer
by spinning it in a spin coater and if
you'd the faster you spin it the more
you know so difficult force we get it
makes the layer thinner so that we can
control the thickness that way and then
what you do is expose your you know
micron scale pattern with ultraviolet
light and etch it away so we can
basically make little holes of almost
any width and depth that we want with
this system the problem is that I don't
have any way to print micron scale stuff
so I've done photolithography before but
I've always used a laser printers
transparency and that's there's no way
to get down to microns with that so I
need like a lensing system but then the
lenses don't pass ultraviolet light and
you know there's a lot of problems
involved so I need your help to figure
out how to pull this off there's a few
interesting ideas that well I'm sure
will come up in the comments but
basically we need to create this you
know about 500 nanometer by 2 micron
pillar and have it really dense on a
surface and something that we can cast
like silicon and then I'm pretty sure
it's going to work and we'll actually
have deco tape okay
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